… Another example of a dearomatizing (3+2) cycloaddition using a Rh III catalyst was developed
by Mascareñas, Gulías, and co-workers 21a as well as by Lam and co-workers, 21b and …

… The groups of Toste and Mascareñas independently demonstrated that the same type of
allene-dienes, when disubstituted at the distal position of the allene (34′), lead to products …

… In 2005 she received the “FPU” PhD fellowship of the Spanish Ministery of Education and
Science and joined the laboratory of Professor José Luis Mascareñas, where she is currently …

Gold(I) complexes featuring electron acceptor ligands such as phosphites and phosphoramidites
catalyze the [4C+2C] intramolecular cycloaddition of allenedienes. The reaction is …

Readily available o-vinylphenols undergo a formal (5 + 2) cycloaddition to alkynes when
treated with catalytic amounts of [Cp*RhCl 2 ] 2 and Cu(OAc) 2 . The reaction, which involves …

Allenes are very versatile synthetic units that are used in many types of catalytic cycloaddition
reactions. Most examples reported so far involve their use as 2C‐atom components, …

Appropriately substituted 2-alkenylphenols undergo a mild formal [3C+2C] cycloaddition
with alkynes when treated with a Rh(III) catalyst and an oxidant. The reaction, which involves …

The development of transition metal catalysts capable of promoting non-natural transformations
within living cells can open significant new avenues in chemical and cell biology. …

The first highly enantioselective intermolecular (4 + 2) cycloaddition between allenes and
dienes is reported. The reaction provides good yields of optically active cyclohexenes …

Conspectus Cycloaddition reactions, by involving the formation of at least two bonds and
one cycle in a single operation, represent one of the more practical ways to assemble carbo- …